McCaw Chemistry

Resources written by Chas McCaw for sixth form chemistry teaching and beyond.

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α-Quartz 3: the axis of the helical chains

Within each unit cell there is one full rotation of each of two alpha helices, which share a silicon atom at each end of the unit cell. Both of the alpha helices in the structure to the left are right-handed. Since the strand of each alpha helix has four silicon atoms in each cell, then with the passing from one silicon atom to the next there must be a rotation of 120 degrees. The structure is most easily visualised using a polyhedral approach and considering the chains of linked tetrahedra that result.

Go to page 4 to look at a polyhedral representation of this structure.

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